Interplay of Phosphido and Phosphine Ligands in Dinuclear Ruthenium Complexes: Implication in the Catalytic Hydroformylation of Ethylene

DOI: 10.1039/DT9920002133

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2133 - 2134 (1992)

Update date:2022-08-17

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Authors:

Beguin, Alain

Boettcher, Hans-Christian

Suess-Fink, Georg

Walther, Bernhard

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Article abstract of DOI:10.1039/DT9920002133

The conversion of the diphenylphosphine complex 1 into the diphenylphosphido complex 2 under a pressure of CO and the conversion of 2 into the ethyldiphenylphosphine complex 3 in the presence of ethylene and water have been studied; high-yield syntheses for the known complex 2 are also reported.

Full text of DOI:10.1039/DT9920002133

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