Remarkable Effects of Metal Ions and Axial Bases on Catalytic and Asymmetric Oxidation of Simple Olefins with a "Twin-coronet" Porphyrin

Article abstract of DOI:10.1016/S0040-4039(00)60964-4

Effect of central metals and oxidants on the catalytic and asymmetric epoxidation of simple olefins was evaluated with a chiral binaphthalene-linked twin-coronet porphyrin catalyst, whose Mn derivative gave superior ees of resultant epoxide than the corre