ETUDE ELECTROCHIMIQUE DE COMPOSES ORGANOMETALLIQUES XII. ACTIVATION DE LA DOUBLE LIAISON N=N DE LA BENZOCINNOLINE PAR LE MONOCHLORURE DE TITANOCENE (Cp2TiCl)2

DOI: 10.1016/S0022-328X(00)99592-5

Source and publish data:

Journal of Organometallic Chemistry p. C11 - C14 (1986)

Update date:2022-08-30

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Authors:

Renaud, S.

Mugnier, Y.

Roullier, L.

Laviron, E.

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Article abstract of DOI:10.1016/S0022-328X(00)99592-5

The condensation at -30 deg C of benzocinnoline (RN=NR) on electrochemically prepared Cp2TiCl yields the titanium(IV) complex Cp2Ti(Cl)N(R)N(R)(Cl)TiCp2 which slowly decomposes into Cp2TiCl2 and benzocinnolinedicyclopentadienyltitanium.

Full text of DOI:10.1016/S0022-328X(00)99592-5

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