ETUDE ELECTROCHIMIQUE DE COMPOSES ORGANOMETALLIQUES XII. ACTIVATION DE LA DOUBLE LIAISON N=N DE LA BENZOCINNOLINE PAR LE MONOCHLORURE DE TITANOCENE (Cp2TiCl)2

Article abstract of DOI:10.1016/S0022-328X(00)99592-5

The condensation at -30 deg C of benzocinnoline (RN=NR) on electrochemically prepared Cp2TiCl yields the titanium(IV) complex Cp2Ti(Cl)N(R)N(R)(Cl)TiCp2 which slowly decomposes into Cp2TiCl2 and benzocinnolinedicyclopentadienyltitanium.