
Chemical Communications p. 1941 - 1942 (1996)
Update date:2022-08-17
Topics:
Abbenhuis, Hendrikus C. L.
Van Herwijnen, Hendrikus W. G.
Van Santen, Rutger A.
A highly active, genuinely heterogeneous catalyst for liquid-phase Diels-Alder reactions of enones results from the silanol centred modification of an incompletely condensed silasesquioxane with trimethylaluminium, the resulting catalytic material being a gel that contains aluminium(III) siloxy functions (Al-O-Si) which are incorporated in a well defined, three-dimensional SiO framework.
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