Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones

DOI: 10.1016/S0040-4039(00)88524-X

Source and publish data:

Tetrahedron Letters p. 7489 - 7492 (1990)

Update date:2022-08-29

Topics:

Authors:

Lloris, Maria E.

Marquet, Jorge

Moreno-Manas, Marcial

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Article abstract of DOI:10.1016/S0040-4039(00)88524-X

The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared.

Full text of DOI:10.1016/S0040-4039(00)88524-X

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