Journal of Physical Chemistry p. 1510 - 1513 (1988)
Update date:2022-08-17
Topics:
He, Y. Z.
Cui, J. P.
Mallard, W. G.
Tsang, W.
The hydrogen atom induced decomposition of aniline was studied by using a heated single-pulse shock tube.Hydrogen atoms were generated from hexamethylethane decomposition at sufficiently high aniline to hexamethylethane concentration so that the main reactions were abstraction of the amine hydrogen and displacement of the amino group.The rate expressions are ka(H+C6H5NH2 -> C6H5NH+H2)=1.8 E11 exp(-5846/T) L/(mol s) and kd(H+C6H5NH2 -> C6H6+NH2)=2.2 E10 exp(-3735/T) L/(mol s) over the temperature range of 1000-1140 K and pressures near 3.3 atm of argon.These rate expressions are compared to earlier results on toluene and phenol.
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