Ligational behaviour of electrochemically synthesized copper(II) complexes of diethyl 2,3-dioxopentanedioate-2-arylhydrazone derivatives

Article abstract of DOI:10.1080/00945719909351721

Cu(II) complexes of diethyl 2,3-dioxopentanedioate-2-arylhydrazone derivatives have been prepared electrochemically. Their ligational behaviour has been studied using elemental analyses, IR and electronic spectra, magnetic moments and thermogravimetric studies. This work revealed that the structure of the synthesized complexes and their spectral behavior depend, to some extent, on the type and nature of substituents on each ligand. The arylhydrazones under investigation act as α-arylhydrazone ester as well as β-keto ester. Electronic spectra suggest a square-planar structure of the complexes.

Full text of DOI:10.1080/00945719909351721

Synthesis and Reactivity in Inorganic and Metal-Organic
Chemistry
ISSN: 0094-5714 (Print) 1532-2440 (Online) Journal homepage: http://www.tandfonline.com/loi/lsrt19
Ligational Behaviour of Electrochemically
Synthesized Copper(II) Complexes of Diethyl 2, 3-
Dioxopentanedioate-2-Arylhydrazone Derivatives
Y. M. Issa , N. T. Abdel-Ghani & M. F. Abo El-Ghar
To cite this article: Y. M. Issa , N. T. Abdel-Ghani & M. F. Abo El-Ghar (1999) Ligational
Behaviour of Electrochemically Synthesized Copper(II) Complexes of Diethyl 2, 3-
Dioxopentanedioate-2-Arylhydrazone Derivatives, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 29:9, 1593-1609, DOI: 10.1080/00945719909351721
To link to this article: http://dx.doi.org/10.1080/00945719909351721
Published online: 23 Apr 2008.
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Date: 07 June 2016, At: 09:10