
Synthesis p. 954 - 956 (1992)
Update date:2022-08-16
Topics:
Denat
Gaspard-Iloughmane
Dubac
The group 14 C-metallated 2(or 3)-furan- and thiophenecarbaldehydes 4-19 have been regioselectively prepared by a one-pot procedure from the corresponding furan- and thiophenecarbaldehydes using lithium N-methylpiperazide/butyllithium or sec-butyllithium/chlorotrialkylsilanes (germanes, tin)/water as sequence of reagents.
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(2016)