Synthesis of (1-Halo-1-alkenyl)trimethylsilanes via gem-Trimethylsilylation of Vinyl Halides

DOI: 10.1246/bcsj.60.777

Source and publish data:

Bulletin of the Chemical Society of Japan p. 777 - 778 (1987)

Update date:2022-08-11

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Authors:

Shimizu, Nobujiro

Shibata, Fumihiro

Tsuno, Yuho

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Article abstract of DOI:10.1246/bcsj.60.777

Various vinyl halides including enol silyl ethers of α-halo ketones and esters give the corresponding (1-halo-1-alkenyl)trimethylsilanes in fair to good yields on treatment with lithium diisopropylamide at Dry Ice temperature in the presence of chlorotrimethylsilane.

Full text of DOI:10.1246/bcsj.60.777

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