THE DIMESITYLBORON GROUP IN ORGANIC SYNTHESIS, IX. A MOST UNUSUAL REACTION : ELECTROPHILIC ATTACK ON SULPHUR IN α-THIOCARBANIONS.

DOI: 10.1016/S0040-4039(00)85126-6

Source and publish data:

Tetrahedron Letters p. 5033 - 5036 (1986)

Update date:2022-08-10

Topics:

Authors:

Pelter, Andrew

Bugden, Gina

Pardasani, Ram

Wilson, John

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Article abstract of DOI:10.1016/S0040-4039(00)85126-6

Predominant alkylation of a boron-stabilised carbanion containing an α-phenylthio group is unprecedentedly on sulphur rather than carbon.Even in lithium phenylthiomethane a similar effect can be observed, its importance being solvent dependant.

Full text of DOI:10.1016/S0040-4039(00)85126-6

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