Journal of Organometallic Chemistry p. 209 - 219 (1972)
Update date:2022-08-10
Topics:
Villieras, Jean
The preparation of magnesium, zinc or lithium malonic or acetoacetic type enolates through halogen-metal interconversion or direct reaction of a metal on the appropriate halogenated compound is reported. The properties of these new reagents (electrophilicity, nucleophilicity and stability) are compared to those of gem-halogenated organometallics and unchelated enolates.
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