Synthesis of Both the Enantiomers of Phoracantholide I; A Defensive Secretion of the Eucarypt Longicorn (Phoracantha synonyma), Employing Microbial Asymmetric Reduction with Immobilized Baker's Yeast

DOI: 10.1246/bcsj.62.608

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Bulletin of the Chemical Society of Japan p. 608 - 610 (1989)

Update date:2022-08-16

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Authors:

Naoshima, Yoshinobu

Hasegawa, Hidenobu

Nishiyama, Tadashi

Nakamura, Akihiro

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Article abstract of DOI:10.1246/bcsj.62.608

Highly optically pure (R)- and (S)-phoracantholide I were synthesized in relatively short steps starting from diethyl 3-oxoglutarate by means of a microbial asymmetric reduction of the intermediate keto acid with immobilized baker's yeast entrapped in gels of κ-carrageenan.

Full text of DOI:10.1246/bcsj.62.608

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