Green Chemistry p. 2830 - 2842 (2013)
Update date:2022-09-26
Topics:
Mitchell, Lorna J.
Lewis, William
Moody, Christopher J.
A practical and robust photo Friedel-Crafts acylation of naphthoquinones is described. Although the reaction proceeds slowly in sunlight, the optimised conditions offer a substantial improvement to those already reported, by the utilisation of a more reliable and practical 'sun-mimicking' light source, a less hazardous solvent system (trifluorotoluene) and faster reaction times. Using these conditions, the reaction scope has been expanded to include functionalised aldehyde and naphthoquinone substrates, affording the desired photo-products in acceptable to excellent yields (17-81%). Factors influencing the regiochemistry of the photo Friedel-Crafts reaction on unsymmetrical naphthoquinones have also been investigated.
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Doi:10.1016/j.tetlet.2013.04.064
(2013)Doi:10.1021/om4000538
(2013)Doi:10.3762/bjoc.9.48
(2013)Doi:10.1016/S0040-4039(00)61318-7
(1992)Doi:10.1016/S0040-4039(01)99231-7
(1961)Doi:10.1248/cpb.39.3132
(1991)