Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2365 - 2380 (1987)
Update date:2022-08-17
Topics:
Brede, Ortwin
Hermann, Ralf
Mehnert, Reiner
Results of pulse-radiolytic model experiments on the auto-oxidation of long-chain n-alkanes and auto-oxidation retardation are presented.In pure n-heptadecane and solutions of di-t-butyl-p-cresol or diphenylamine the reaction of alkyl radicals with oxygen and the corresponding competition reactions with the stabilizer prototypes have been characterized by spectroscopic and kinetic data.A reaction mechanism describing the radiation-induced processes within the system long-chain n-alkane-oxygen-stabilizer is discussed.
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