Alkylmetal Asymmetric Reduction. 17. Stereochemical Course of Ketone Reduction by β-Branched Alkyl Derivatives of Beryllium and Aluminum

DOI: 10.1021/jo00361a017

Source and publish data:

Journal of Organic Chemistry p. 2030 - 2033 (1986)

Update date:2022-08-16

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Authors:

Falorni, Massimo

Lardicci, Luciano

Rosini, Carlo

Giacomelli, Giampaolo

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Article abstract of DOI:10.1021/jo00361a017

(R)-(2-Methylbutyl)beryllium chloride and tri-cis-myrtanylaluminum have been prepared; both these new organometallic derivatives are able to provide enantioselective reduction of prochiral ketones.Further investigations on the use of cis-myrtanylberyllium

Full text of DOI:10.1021/jo00361a017

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