Tetrahedron Letters p. 7915 - 7916 (1993)
Update date:2022-08-02
Topics:
Czernecki
Randriamandimby
Anti-Markovnikov azido-phenylselenylation of diversely protected glycals affords protected phenyl 2-azido-2-deoxy-α-selenoglycopyranosides. From D-glucal, the α-manno and α-gluco isomers are obtained, whereas from D-galactal, a complete stereocontrol is observed, affording exclusively the α-galacto isomer in 70% yield.
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