Stereoselective reduction of ketones by histidine-alkoxysilane complexes: The role of imidazole in nucleophilic substitution at silicon

DOI: 10.1016/S0040-4039(99)00543-2

Source and publish data:

Tetrahedron Letters p. 3507 - 3510 (1999)

Update date:2022-08-28

Topics:

Authors:

LaRonde, Frank J.

Brook, Michael A.

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Article abstract of DOI:10.1016/S0040-4039(99)00543-2

The reduction of carbonyl compounds with transient, hypervalent silicon hydrides is described. Trialkoxysilanes, upon activation by a catalytic amount of lithium imidazolide or the mono or dilithium salt of histidine, but not by neutral imidazole or histi

Full text of DOI:10.1016/S0040-4039(99)00543-2

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