Potassium 3-oxa-ω-fluorosulfonylperfluoropentanoate (FO2SCF2CF2OCF2CO2K), a low-temperature trifluoromethylating agent for organic halides; its α-carbon-oxygen bond fragmentation

DOI: 10.1016/0022-1139(96)03438-0

Source and publish data:

Journal of Fluorine Chemistry p. 177 - 181 (1996)

Update date:2022-08-11

Topics:

Authors:

Long, Zheng-Yu

Duan, Jian-Xin

Lin, Yuan-Bin

Guo, Cai-Yun

Chen, Qing-Yun

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-1139(96)03438-0

The trifluoromethylation of organic halides with FO₂SCF₂CF₂OCF₂CO₂K (1) in DMF can be accomplished at 45 °C which is advantageous for thermally sensitive substrates. α-Carbon-oxygen bond fragmentation of 1 and the related β-carbon-oxygen bond scission are discussed.

Full text of DOI:10.1016/0022-1139(96)03438-0

Products guided by the article

Product name:1,1,1-TRIFLUOROBUTENE-3

Cas No:1524-26-1

R&D Labs maybe for 1524-26-1

Jiangsu Seed Chem Co.,Ltd.

Contact:86-513-84128750/13773795976

Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Junkai (Tianjin) Chemical Co., Ltd.

website:http://www.junkaichem.com

Contact:86-22-85689515

Address:Room 8-501, Building K2, The Hi-Tech Green Industrial Base, No.6, 6th Road, Hi-Tech Development Road, Tianjin Hi-Tech IndustrialPark, Tianjin, China.
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
ShangHai Ruiyi Medical Technology Co.,Ltd.

Contact:+86-21-54718086

Address:No951 Jianchuan RD，Minhang District
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China

Relevant to this article

Iridium complexes of chiral diamines containing carbon and nitrogen stereocentres: Synthesis, structure and evaluation as transfer hydrogenation catalysts

Doi:10.1039/b812699b
(2009)
Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents

Doi:10.1002/chem.202101475
(2021)
(13)C NMR study of reorientational dynamics in Ru3(Co)9(μ(3)-Co)(μ(3)-NPh). Relaxation time analysis in the non-motional narrowing regime

Doi:10.1016/0020-1693(95)04610-L
(1995)
Novel synthetic routes of 3-methoxypropanal from glycerol

Doi:10.1080/00397911.2010.486502
(2011)
Doi:10.1139/v69-247
(1969)
Doi:10.1021/ja01319a063
(1934)

Article Doi