A General Route for the Synthesis of Tetranuclear Clusters containing Closed Triruthenium and Triosmium Triangles

DOI: 10.1039/DT9860002515

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2515 - 2518 (1986)

Update date:2022-08-16

Topics:

Authors:

Foulds, Gary A.

Johnson, Brian F. G.

Lewis, Jack

Sorrell, Robert M.

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Article abstract of DOI:10.1039/DT9860002515

The cluster compounds (M = Ru or Os, M'= Co) and (M = Ru or Os; M'= Fe, Ru, or Os) have been prepared in good yield by the reaction of an appropriate tetracarbonylmetalate with the bis(acetonitrile) complexes, M = Ru or Os).The anionic clusters have been protonated, where possible, to give the corresponding neutral hydride clusters.In addition to known tetranuclear cluster synthesised by this method, we report the new cluster compounds , , and .

Full text of DOI:10.1039/DT9860002515

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