Enantioselective pseudomonas fluorescens (P. Cepacia) Lipase-Catalyzed irreversible transesterification of 2-Methyl-1,2-Diols in an organic solvent

DOI: 10.1016/S0957-4166(00)86267-9

Source and publish data:

Tetrahedron Asymmetry p. 1921 - 1924 (1994)

Update date:2022-08-18

Topics:

Authors:

Ferraboschi

Casati Casati

Grisenti

Santaniello

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Article abstract of DOI:10.1016/S0957-4166(00)86267-9

The Pseudomonas fluorescens (P. cepacia) lipase-catalyzed irreversible transesterification of 2-phenyl-1,2-propanediol in is not enantioselective, whereas the diols 1b and 1c are enzymatically resolved with the same procedure to (S)-1b and 1c (>98 and 92% e.e.) and the (R)-acetates 2b and 2c (92% e.e.).

Full text of DOI:10.1016/S0957-4166(00)86267-9

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