Unusual Non-Oxidative Pummerer Rearrangement of γ-Trifluoro-β-aminosulfoxides

DOI: 10.1016/0040-4039(95)01470-3

Source and publish data:

Tetrahedron Letters p. 7301 - 7304 (1995)

Update date:2022-08-11

Topics:

Authors:

Arnone, Alberto

Bravo, Pierfrancesco

Bruche, Luca

Crucianelli, Marcello

Vichi, Lucia

Zanda, Matteo

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Article abstract of DOI:10.1016/0040-4039(95)01470-3

Trifluoroacetic anhydride promoted Pummerer rearrangement of γ-trifluoro-β-aminosulfoxides 1 follows an unusual pathway, in which a migration of the p-tolylthio group to the nitrogen atom provides the corresponding α-sulfenamidotrifluoroacetates 5.The usu

Full text of DOI:10.1016/0040-4039(95)01470-3

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