Tin(II) Chloride Catalyzed Synthesis of β-D-Ribonucleosides

DOI: 10.1246/cl.1994.2089

Source and publish data:

Chemistry Letters p. 2089 - 2092 (1994)

Update date:2022-08-31

Topics:

Authors:

Mukaiyama, Teruaki

Matsutani, Takafumi

Shimomura, Naoyuki

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Article abstract of DOI:10.1246/cl.1994.2089

Several β-D-ribonucleosides are stereoselectively synthesized in high yields from methyl 2,3,5-tri-O-benzoyl-β-D-ribofuranosyl carbonate and trimethylsilylated nucleoside bases such as pertrimethylsilylated uracil and adenine under mild conditions by using a catalytic amount of tin(II) chloride, a weak Lewis acid.

Full text of DOI:10.1246/cl.1994.2089

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