Journal of Organic Chemistry p. 4638 - 4641 (1988)
Update date:2022-08-29
Topics:
Branchaud, Bruce P.
Choi, Youngshin Lee
The first examples of cobaloxime-mediated radical alkyl-heteroaromatic cross-coupling, replacing a C-H in the protonated heteroaromatic with a C-alkyl, are accomplished via anaerobic visible light photolysis of 95percent EtOH solutions of primary and secondary alkyl cobaloximes, RCoIII(dmgH)2py (dmgH = dimethylglyoxime monoanion), and pyridinium, quinolinium, 4-methylpyridinium, benzothiazolium, and benzimidazolium p-toluenesulfonate.
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