Carbohydrate Research p. 237 - 246 (1985)
Update date:2022-08-30
Topics:
Makkee, Michiel
Kieboom, Antonius P. G.
Bekkum, Herman van
A process involving both a bio- and a chemo-catalyst has been applied for the conversion of D-glucose/D-fructose mixtures into D-mannitol.Good yields (62-66percent) were obtained by using D-glucose isomerase immobilised on silica in combination with a copper-on-silica catalyst (water, pH ca 7, 70 deg C, 50 kg/cm2 of hydrogen, trace amounts of buffer, Mg(II), borate, and EDTA).Non-enzymic isomerisation and degradation reactions are negligible under these reaction conditions.
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Doi:10.1248/cpb.42.1101
(1994)Doi:10.1007/s10593-006-0110-6
(2006)Doi:10.1007/s11164-015-2123-1
(2016)Doi:10.1021/ic5027043
(2015)Doi:10.1021/ja9910560
(1999)Doi:10.1021/ac60062a016
(1952)
