Journal of the American Chemical Society p. 6893 - 6897 (1981)
Update date:2022-08-16
Topics:
Dunn, Wendell W.
Aikawa, Yosihiro
Bard, Allen J.
Studies of the previously reported production of amino acids (glycine, alanine, serine, aspartic acid, glutamic acid) from methane, ammonia, and water in contact with irradiated suspensions of Pt/TiO2 were extended.Products were analyzed by LC, HPLC, and coupled GC/mass spectroscopy.Analysis of product mixtures also shows the presence of MeOH, EtOH, and CH3NH2 as products of the photoprocess.Experiments with nitrogen-15 labeled ammonia showed that the nitrogen in the amino acids originated with the NH3 rather than from contaminants.Amino acids were also produced from the CH4-NH3-H2O mixture during decomposition of hydrogen peroxide at Pt foil.A mechanism for the reaction based on free-radical reactions initiated by hydroxyl radical produced at the irradiated catalyst is proposed.
View MoreShijiazhuang Sdyano Fine Chemical Co., Ltd
Contact:+86-311-89830448
Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
website:http://www.alwaychem.com
Contact:+86-532-8586-4000, 8586-5000
Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001
Suzhou CarbonWell Pharma-Tech Co., Ltd
Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602
Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
website:http://www.shengmaochem.com
Contact:86-27-82853423, 82819281
Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
Shanghai Synmedia Chemical Co., Ltd
Contact:+86-21-38681880
Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Doi:10.1021/acs.orglett.7b01573
(2017)Doi:10.1021/jo00800a034
(1971)Doi:10.1021/js970117u
(1998)Doi:10.1021/ja01333a037
(1933)Doi:10.1038/nchem.2345
(2015)Doi:10.1039/b609198a
(2006)