USEFUL CHIRAL LACTONES DERIVED FROM CIS-BICYCLOOCTAN-3,7-DIONE VIA ASYMMETRIC DEPROTONATION

DOI: 10.1016/S0957-4166(00)82377-0

Source and publish data:

Tetrahedron Asymmetry p. 699 - 702 (1990)

Update date:2022-08-17

Topics:

Authors:

Leonard, John

Hewitt, Jacqueline D.

Ouali, Dehimi

Rahman, Shirley K.

Simpson, Stephen J.

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Article abstract of DOI:10.1016/S0957-4166(00)82377-0

The monoketal derived from cis-bicyclo<3.3.0>octane-3,7-dione was deprotonated using chiral lithium amide bases and the enolates were trapped as either enol acetates or trimethylsilyl enol ethers.Oxidative cleavage of the enol derivatives provided useful

Full text of DOI:10.1016/S0957-4166(00)82377-0

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