Tetrahedron Letters p. 9823 - 9826 (1998)
Update date:2022-08-24
Topics:
Sarobe, Martin
Kwint, Huibert C.
Fleer, Theun
Jenneskens, Leonardus W.
Wesseling, Jolanda
FVT of acenaphtho[1,2-a]acenaphthylene (1) gave acenaphtho[1,2- elacenaphthylene (2). cyclopenta[cd]perylene (3) and cyclopenia[rst]benzo[hi]chrysene (4). The formation of 3 and 4 indicates that, besides ring contraction/ring expansion of 1 giving 2, homolytic scission of a five-membered ring carbon-carbon single bond of 1 is an important competitive process.
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