Tetrahedron p. 4333 - 4346 (1995)
Update date:2022-08-29
Topics:
Dzhemilev, U. M.
This paper describes some applications of a new reaction of catalytic cyclometallation of α-olefins, norbornenes and their derivatives, and 1,2-disubstituted acetylenes with organomagnesium and organoaluminium compounds effected by zirconium catalysts, leading to a series of five and macrocyclic heterocycles containing magnesium and aluminium.
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