Journal of the Chemical Society. Chemical communications p. 777 - 778 (1984)
Update date:2022-08-30
Topics:
Boudjouk, Philip
Sooriyakumaran, Ratnasabapathy
The action of lithium metal on tetrakis(dimethylbromosilyl)silane or tetrakis(dimethylchlorosilyl)silane in tetrahydrofuran produces the first spiropentasilane, a highly strained polysilane that undergoes efficient cleavage reactions with lithium aluminium hydride, methylmagnesium bromide, and phosphorus pentachloride.
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