A novel photorearrangement of aryl naphthylmethyl ethers. Formation of cyclohexa-2,4-dienone derivatives

DOI: 10.1016/S0040-4039(98)00877-6

Source and publish data:

Tetrahedron Letters p. 4683 - 4686 (1998)

Update date:2022-08-11

Topics:

Authors:

Yoshimi, Yasuharu

Sugimoto, Akira

Maeda, Hajime

Mizuno, Kazuhiko

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Article abstract of DOI:10.1016/S0040-4039(98)00877-6

Irradiation of a benzene solution containing 1-methoxycarbonyl-2- naphthylmethyl 2,6-dimethyl substituted phenyl ethers (1a,b) afforded cyclohexa-2,4-dienone derivatives (2a,b) as initial rearranged products via C-O bond cleavage and meta substituted phenols (3a,b) which were formed by subsequent photorearrangement of 2a,b.

Full text of DOI:10.1016/S0040-4039(98)00877-6

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