Chemistry Letters p. 1127 - 1130 (1980)
Update date:2022-08-16
Topics:
Tashiro, Masashi
Yamato, Takehiko
Treatment of 2,7-di-tert-butyl-trans-10b,10c-dialkyl-10b,10c-dihydropyrenes 5a-5c with bromine afforded the corresponding tetrabromides 7a-7c in good yields, respectively.The tetrachloro derivative of 5a was also obtained in 40percent yield by the treatment of 5a with SO2Cl2.The bromination of 5a-5c with bromine in the presence of Fe powder gave the dealkylated compound 2,7-di-tert-4,5,9,10-tetrabromopyrene 8 in good yields, respectively.When 5a-5c were treated with I2, 2,7-di-tert-butylpyrene 9 was obtained in good yields, in all cases.
View More
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD
Contact:+86-571-88932183
Address:Hangzhou
Guangzhou PI & PI Biotech Inc. Ltd.
Contact:+86-20-81716320
Address:Suite 501,198 Kaiyuan Ave.,Science City, Guangzhou,China
Contact:+86-512-56795332
Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
zhejiang huangyan wanfeng pharm chem co.ltd
Contact:+86-576- 84160728
Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Hangzhou Hysen Pharma co.,Ltd.
website:http://www.hysenpharma.cn/
Contact:0086-571-88298791
Address:#701,Gudun Road Hangzhou
Doi:10.1016/j.tetlet.2012.04.119
(2012)Doi:10.1039/c5ra14878b
(2015)Doi:10.1021/jo01039a518
(1963)Doi:10.1246/bcsj.56.1855
(1983)Doi:10.1039/c2dt12133f
(2012)Doi:10.1039/c6nj02089e
(2016)
