Journal of the Chemical Society. Chemical communications p. 1049 - 1050 (1990)
Update date:2022-09-26
Topics:
Vargaftik, M. N.
Stolarov, I. P.
Moiseev, I. I.
Methane has been oxidized stoicheiometrically by cobalt(III) trifluoroacetate in CF3CO2H solution at 150-180 deg C and 10-40 atm to give methyl trifluoroacetate in 90 +/- 10percent yield based on COIII, which is reduced to CoII; in the presence of O2 (1-5 atm) the reaction becomes catalytic with respect to the cobalt(III) salt, giving methyl trifluoroacetate as the sole product of the oxidation of methane by dioxygen.
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Doi:10.1021/ja990219h
(1999)Doi:10.1016/0040-4020(72)88013-X
(1972)Doi:10.1021/jm9911074
(1999)Doi:10.1021/jo982496x
(1999)Doi:10.1016/S0040-4020(99)00500-1
(1999)Doi:10.1271/bbb.63.1304
(1999)