TEMPERATURE DEPENDENCE OF POLAR AND STERIC EFFECTS IN CCl2 CYCLOADDITIONS

DOI: 10.1016/S0040-4039(00)87668-6

Source and publish data:

Tetrahedron Letters p. 3557 - 3560 (1982)

Update date:2022-08-29

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Authors:

Giese, Bernd

Neumann, Carola

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Article abstract of DOI:10.1016/S0040-4039(00)87668-6

In cycloadditions of CCl₂ activation enthalpies increase with bulky substituents at the alkenes (Table I, Figure II), whereas by polar groups only activation entropies are changed.

Full text of DOI:10.1016/S0040-4039(00)87668-6

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