
Journal of the Chemical Society. Chemical communications p. 643 - 644 (1985)
Update date:2022-08-30
Topics:
Cadogan, J. I. G.
Hickson, Clare L.
Hutchison, H. Susan
McNab, Hamish
Flash vacuum pyrolysis studies of substituted benzyl, phenylaminyl, and phenoxyl radicals have revealed three new classes of reactions: formation of five-membered ring products via intramolecular abstracion of an aromatic hydrogen atom, formation of six-membered rings via spirodienyl radical intermediates, and isomerisation of o-phenoxybenzyl into o-benzylphenoxyl radicals and vice versa.
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