Uridine diphospho-α-D-gluco-hexodialdose: Synthesis and kinetic competence in the reaction catalyzed by UDP-glucose dehydrogenase

DOI: 10.1002/anie.199715201

Source and publish data:

Angewandte Chemie - International Edition in English p. 1520 - 1522 (1997)

Update date:2022-08-17

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Authors:

Campbell

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Article abstract of DOI:10.1002/anie.199715201

The elusive aldehyde 1 has never been trapped nor detected during the enzymatic oxidation of UDP-glucose to UDP-glucuronic acid. Here the synthesis of 1 is reported; it proved to be kinetically competent to serve as an intermediate in the reaction catalyzed by UDP-glucose dehydrogenase.

Full text of DOI:10.1002/anie.199715201

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