Helvetica Chimica Acta p. 59 - 62 (1987)
Update date:2022-08-10
Topics:
Klaic, Branimir
Raza, Zlata
Sankovic, Mauricio
Sunjic, Vitomir
Heptamolybdate-ion(HM)-catalyzed C(2) epimerization of D-glucose and racemization of D-glyceraldehyde proceed with comparable rates and activation parameters; HM catalyzes the isomerisation of glucal and galactal triacetates as well.For all of the above transformations, a common, new mechanism is proposed that invokes stabilization of 3-oxa-allylic cation species by the central Mo(VI) atom.
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