484
LERMONTOVA et al.
(Carom–O–C); 1158, 1101 (C–F). Found, %: C 60.89; H
3.37; F 5.08; N 11.35; Yb 12.46. C72H45F4N12O7Yb.
Calculated, %: C 60.09; H 3.15; F 5.28; N 11.68; Yb
12.02.
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trifluoroacetic acid was stirred for 30 min at room
temperature. The mixture was diluted with 30 mL of
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Tetrakis(4-benzyloxyphenyl)tetracyanoporphyrazine
(12). Yield 83%, black solid, mp > 300°C. IR
spectrum, ν, cm–1: 3400 (N–H), 2205 (C≡N); 1687,
1678 (C=N), 1600 (C=C); 1218, 1025 (Carom–O–C).
UV spectrum (THF), λmax, nm: 361, 397 (Soret band),
617 (Q band). Found, %: C 76.70; H 4.16; O 5.4; N
14.02. C72H46N12O4. Calculated, %: C 75.64; H 4.06;
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Tetracyanotetrakis[4-(4-fluorobenzyloxy)phenyl]-
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IR spectrum, ν, cm–1: 3403 (N–H), 2201 (C≡N), 1681
(C=N), 1603 (C=C); 1218, 1038 (Carom–O–C); 1164,
1102 (C–F). UV spectrum (THF), λmax, nm: 356, 397
(Soret band), 610 (Q band). Found, %: C 72.16; H
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C 71.16; H 3.48; F 6.25; N 13.83.
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ACKNOWLEDGMENTS
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This study was performed under financial support
by the Russian Foundation for Basic Research (project
nos. 16-33-50217-mol_nr, 16-34-60117- mol_a_dk,
15-02-05468-a) and by the Ministry of Education and
Science of the Russian Federation (project
no. 14.Z50.31.022).
RUSSIAN JOURNAL OF GENERAL CHEMISTRY Vol. 87 No. 3 2017