Journal of Organic Chemistry p. 3945 - 3946 (1985)
Update date:2022-08-22
Topics:
Piccolo, Oreste
Spreafico,Franca
Visentin, Giuseppina
Valoti, Ermanno
The alkylation of benzene with (S)-methyl 2-<(chlorosulfonyl)oxy>- or 2-(mesyloxy)propionate, in the presence of aluminum chloride, affords (S)-methyl 2-phenylpropionate in good chemical (50-80percent) and excellent optical yield (<*>97percent as determined by rotation), with inversion of configuration at the attacking carbon atom.
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