New chemistry of cyclic, s-trans-enaminones: Addition of Grignard reagents to enaminones derived from 2-methylcyclohexane-1,3-dione

DOI: 10.1016/0040-4039(96)00725-3

Source and publish data:

Tetrahedron Letters p. 3823 - 3824 (1996)

Update date:2022-08-16

Topics:

Authors:

Shawe, Thomas T.

Landino, Linda M.

Ross, Andrew A.

Prokopowicz, Anthony S.

Robinson, Patrice M.

Cannon, Annatina

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Article abstract of DOI:10.1016/0040-4039(96)00725-3

Grignard reagents add to cyclic s-trans enaminones to give the cycloalkenone after aqueous hydrolysis. In some cases a competitive double addition takes place. These reactions have been found to be solvent- and reagent-selective.

Full text of DOI:10.1016/0040-4039(96)00725-3

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