Journal of Organic Chemistry p. 3281 - 3283 (1994)
Update date:2022-08-11
Topics:
Martina, Stefano
MacDonald, Scott A.
Enkelmann, Volker
The problem of synthesizing photosensitive urethanes of the highly sterically hindered 2,2,6,6-tetramethylpiperidine is solved by first preparing the 1-chlorocarbonyl derivative which was shown to react with a series of o-nitrobenzylic alcohols, including 2,6-dinitrobenzyl alcohol.These products are potential photogenerators of this amine.Full characterization is reported, along with a crystal structure.
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