A NEW METHOD OF OLEFIN SYNTHESIS. COUPLING OF LITHIUM DIALKYLCUPRATES WITH ENOL TRIFLATES

DOI: 10.1016/S0040-4039(00)77845-2

Source and publish data:

Tetrahedron Letters p. 4313 - 4316 (1980)

Update date:2022-08-11

Topics:

Authors:

McMurry, John E.

Scott, William J.

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Article abstract of DOI:10.1016/S0040-4039(00)77845-2

Enol trifluoromethanesulfonates react with lithium dialkylcuprates to give the coupling products in high yields.The reaction is stereoselective and is successful with a wide variety of organocuprates , including methyl, butyl, phenyl, vinyl, and cycloprop

Full text of DOI:10.1016/S0040-4039(00)77845-2

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