Time-Resolved Observation of the Formation of CF2O and CFClO in the CF2Cl + O2 and CFCl2 + O2 Reactions. The Unimolecular Elimination of Cl Atoms from CF2ClO and CFCl2O Radicals

Article abstract of DOI:10.1021/j100183a046

The unimolecular elimination of chlorine atoms from CF2ClO and CFCl2O radicals has been observed at 238 and 298 K and at 4-20 Torr total pressure by measurement of the rate of formation of the carbonyl halide product in real time.The fragment ion (CFO)+ w