Fluorinated Ketene Dithioacetals. 2. Synthesis of 2-Hydroperfluoro Acid Derivatives from Perfluoroketene Dithioacetals

DOI: 10.1021/jo00053a010

Source and publish data:

Journal of Organic Chemistry p. 29 - 31 (1993)

Update date:2022-08-11

Topics:

Authors:

Muzard, Murielle

Portella, Charles

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Article abstract of DOI:10.1021/jo00053a010

Perfluoroketene dithioacetals were prepared in high yields from perfluoroaldehyde hydrates via their thioacetalization (TiCl4/CH2Cl2) followed by basic phase transfer catalyzed HF elimination.Acidic hydrolysis (CF3CO2H, H2O) and then transesterification (EtOH, Ti(OiPr)4) yielded S-alkyl 2-hydroperfluoro thioesters and ethyl 2-hydroperfluoro esters, respectively.

Full text of DOI:10.1021/jo00053a010

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