Synlett p. 2508 - 2512 (2008)
Update date:2022-08-17
Topics:
Bartoli, Gabriele
Cacchi, Sandro
Fabrizi, Giancarlo
Goggiamani, Antonella
The palladium-catalyzed hydroarylation of arenediazonium tetrafluoroborates with norbornene derivatives and analogues in the presence of Pd(OAc) 2 and i-Pr3SiH in THF affords hydroarylation products containing the added aryl unit in the exo position in good to high yields. The reaction tolerates a variety of useful functional groups and can be performed as a one-pot procedure generating the arenediazonium salt in situ. Georg Thieme Verlag Stuttgart.
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(2021)Doi:10.1021/ja02212a006
(1912)
