Reduction of Carbon Monoxide on a Mediated and Partially Immersed Electrode

DOI: 10.1039/f19858101569

Source and publish data:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1569 - 1576 (1985)

Update date:2022-08-10

Topics:

Authors:

Ogura, Kotaro

Watanabe, Hiroyasu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/f19858101569

The reduction of carbon monoxide into methanol has been performed using Everitt's salt IIII(CN)6>> as a mediator in the presence of homogeneous catalysts at a three-phase (electrode/solution/gas) interface.These conditions enhance the reduction of CO owing to the rapid transport of CO to the active zone of the electrode.The logarithm of the reduction current is linearly related to log (time) with a slope of -1/2 and reaches a constant value after an extensive period of polarization.A theoretical equation for the current against time curve is derived based on a surface-diffusion model in which CO from the gas phase is first adsorbed on the electrode surface and then diffuses along the surface toward the intersection of the three phases; the computed plot of current against time fits the experimental one well.

Full text of DOI:10.1039/f19858101569

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Formaldehyde

Cas No:50-00-0

R&D Labs maybe for 50-00-0

Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Tractus Company Limited

Contact:+852-8198 2399

Address:9E, Leapont Industrial Building, 18-28 Wo Liu Hang Road, Shatin, New Territories, Hong Kong
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
chengdu firsterchem Pharmaceutical Co., Ltd.

Contact:028-66825849

Address:chengdu
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China

Relevant to this article

THE PRODUCTION OF CLASS-II MIXED-VALENCE COMPLEXES IN THE REDOX REACTION BETWEEN DITHIOMALONAMIDE AND PLATINUM(IV) OR PALLADIUM(IV).

Doi:10.1039/DT9840001975
(1984)
Synthesis of bacterial metabolites of polycyclic aromatic hydrocarbons: Benzochromenones, o-carboxyvinylnaphthoates, and o-substituted aryl-α-oxobutenoates

Doi:10.1080/00397910500214367
(2005)
Ruthenium-based catalytic systems incorporating a labile cyclooctadiene ligand with N-heterocyclic carbene precursors for the atom-economic alcohol amidation using amines

Doi:10.3390/molecules23102413
(2018)
Antiparasitic activity of natural and semi-synthetic tirucallane triterpenoids from Schinus terebinthifolius (anacardiaceae): Structure/activity relationships

Doi:10.3390/molecules19055761
(2014)
High ion content siloxane phosphonium ionomers with very low T _g

Doi:10.1021/ma5001546
(2014)
Asymmetric epoxidation of allyl alcohol: Efficient routes to homochiral β-adrenergic blocking agents

Doi:10.1021/jo00369a032
(1986)

Article Doi