Phytochemistry p. 2723 - 2726 (1983)
Update date:2022-08-11
Topics:
Grandi, Romano
Pagnoni, Ugo M.
Pinetti, Adriano
Trave, Roberto
Iridodial is a very efficient precursor of dolicholactone in Teucrium marum.In the biogenetic formation of the lactone ring a hydride shift from C-1 to C-10 is observed.Citronellol and its 10-hydroxy derivative are preferred as precursors with respect to the C-2/C-3 unsaturated analogues. - Key Word Index: Teucrium marum; Labiate; dolicholactone; monoterpene biosynthesis; iridane skeleton; hydride shift.
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