(NMCp)2TiCl2-CATALYZED REDUCTION OF ALIPHATIC, AROMATIC AND α,β-UNSATURATED KETONES BY GRIGNARD REAGENT

DOI: 10.1016/S0040-4039(00)80430-X

Source and publish data:

Tetrahedron Letters p. 4113 - 4114 (1988)

Update date:2022-08-17

Topics:

Authors:

Zhang, Yongmin

Hu, Zuyao

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Article abstract of DOI:10.1016/S0040-4039(00)80430-X

Aliphatic, aromatic and α,β-unsaturated ketones were readily reduced to the corresponding secondary alcohols by iso-propylmagnesium bromide in the presence of a catalytic amount of bis(neomenthylcyclopentadienyl)titanium dichloride.A possible mechanism is discussed.

Full text of DOI:10.1016/S0040-4039(00)80430-X

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