MANNICH REACTIONS OF Π-EXCESSIVE HETEROCYLES USING BIS-(DIALKYLAMINO)METHANES AND ALKOXYDIALKYLAMINOMETHANES ACTIVATED WITH ACETYL CHLORIDE OR SULPHUR DIOXIDE

DOI: 10.1016/0040-4039(88)85070-6

Source and publish data:

Tetrahedron Letters p. 2997 - 3000 (1988)

Update date:2022-08-17

Topics:

Authors:

Eyley, Stephen C.

Heaney, Harry

Papageorgiou, George

Wilkins, Robert F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(88)85070-6

Π-Excessive heterocyles react rapidly with bis(dialkylamino)methanes (aminals) and alkoxydialkylaminomethanes (aminol ethers) in acetonitrile to afford Mannnich bases in good yields when ativated by means of an acidi reagent suh as acetyl chloride or sulphur dioxide: the principal ompound studied was N-methylpyrrole.

Full text of DOI:10.1016/0040-4039(88)85070-6

Products guided by the article

Product name:3-(N,N-dimethylaminomethyl)-1-methylindole

Cas No:52972-61-9

R&D Labs maybe for 52972-61-9

Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
Hangzhou utanpharma Co., Ltd

Contact:0571-86821378 ,86820258,56836287,56830923,

Address:Block D ,20F, Tianyuan Building,No.508, Wensan RD, 310013,Hangzhou Zhejiang China
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
Shanghai agrotree chemical co.,ltd.

Contact:+86-21-50117563

Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China

Relevant to this article

Dry photochemical synthesis of hydrotalcite, γ-Al₂O ₃ and TiO₂ supported gold nanoparticle catalysts

Doi:10.1016/j.jphotochem.2011.08.013
(2011)
Deep levels associated with dislocation annihilation by Al pre-seeding and silicon delta doping in GaN grown on Si(111) substrates

Doi:10.1002/pssa.200723481
(2008)
MgBr ₂ · OEt ₂: A Lewis Acid Catalyst for the O - And N -Boc Protection of Phenols and Amines

Doi:10.1080/00397911.2014.976348
(2015)
Reaction of Diphenylcarbene with Diphenyldiazomethane

Doi:10.1021/jo00242a040
(1988)
A short and efficient route to novel scyphostatin analogues

Doi:10.1021/ol0164132
(2001)
Novel efficient synthesis of 1-azabicyclo[1.1.0]butane and its application to the synthesis of 1-(1,3-thiazolin-2-yl)azetidine-3-thiol useful for the pendant moiety of an oral 1β-methyicarbapenem antibiotic L- 084

Doi:10.1016/S0040-4039(99)00603-6
(1999)

Article Doi