MANNICH REACTIONS OF Π-EXCESSIVE HETEROCYLES USING BIS-(DIALKYLAMINO)METHANES AND ALKOXYDIALKYLAMINOMETHANES ACTIVATED WITH ACETYL CHLORIDE OR SULPHUR DIOXIDE

DOI: 10.1016/0040-4039(88)85070-6

Source and publish data:

Tetrahedron Letters p. 2997 - 3000 (1988)

Update date:2022-08-17

Topics:

Authors:

Eyley, Stephen C.

Heaney, Harry

Papageorgiou, George

Wilkins, Robert F.

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Article abstract of DOI:10.1016/0040-4039(88)85070-6

Π-Excessive heterocyles react rapidly with bis(dialkylamino)methanes (aminals) and alkoxydialkylaminomethanes (aminol ethers) in acetonitrile to afford Mannnich bases in good yields when ativated by means of an acidi reagent suh as acetyl chloride or sulphur dioxide: the principal ompound studied was N-methylpyrrole.

Full text of DOI:10.1016/0040-4039(88)85070-6

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