Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1100 - 1101 (1992)
Update date:2022-08-17
Topics:
Dzhemilev, U. M.
Khusnutdinov, R. I.
Shchadneva, N. A.
The strictly regioselective hydrocarboxylation of vinyl acetate to ethylidene diacetate by acetic acid formed in situ from vinyl acetate was realized for the first time with Rh(PPh3)3Cl as catalyst.The transformation of vinyl acetate into benzene, acetophenone, and acetylene was also realized. Keywords: Hydrocarboxylation, vinyl acetate, metal complex catalyst.
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(1963)
