Journal of Organic Chemistry p. 1779 - 1780 (1983)
Update date:2022-08-11
Topics:
Current, Steven P.
A new catalyst system, palladium(II) acetate, cobalt(II) acetate, triphenylphosphine, and 1,4-benzoquinone, produces oxalate esters in high selectivity from carbon monoxide, oxygen, and alcohol.Up to 140 mol of dimethyl oxalate is obtained per mole of palladium while only traces of dimethyl carbonate or methyl formate are formed.
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